For the first GEEK mold instructable I've chosen the Star Wars Stormtrooper mold for "casting" ice "cubes" or chocolate or anything else you can think of - the cool thing is to fill the mold with some fruit syrup and have some improvised popsicle...
As always with 3D printing, you can not do anything without 3D model created by 3D modeling or 3D scanning - I use Rhinoceros for all of my modelings but you can use anything you like - there are bunch of free modeling tools out there so go and explore. One thing you need to take care of, when talking about 3D printing, is creating a so called "water tight model" or WTM.This WTM in plain words marks that your design should have no holes and "leaks" where water could came out if in theory you would fill it up. You should not have objects without volume (plain surfaces or curves) - everything needs to be a solid so the printer can make it.
The best way to make sure you have no errors (holes, overlapping triangles, bad edges, etc) which could affect quality of the print, is to use some of the specialized softwares for 3DP preparation - a good free solutions are MiniMagics and MeshLab.
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